Coastal ecosystem change in Asia: hypoxia,eutrophication, and nutrient conditions

Journal of Oceanography -     

烃源岩不同性质有机酸的分离及其检测方法

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。     

Concurrent Determination of U‐Pb Age and REE Mass Fractions of Zircon by High Mass Resolution SIMS

A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate ²⁰⁶Pb/²³⁸U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties.     

碳化对加填料氯氧镁胶凝材料力学性能的影响

以添加不同掺量填料的氯氧镁水泥(MOC)试件为基体,在空气和碳化箱中分别养护至规定龄期,研究碳化对掺加填料MOC力学性能的影响,并与空气环境进行对比,运用XRD和SEM分析碳化后水化产物和微观结构的变化规律。结果表明,28 d龄期内,随着填料掺量的增加MOC试件碳化后的抗折强度均有所增加,碳化后的抗压强度均有提升,碳化过程反应生成了MgCO_3,不同碳化龄期的主要物相均为5Mg(OH)_2·MgCl_2·8H_2O(5相),而掺加填料不影响MOC的水化产物的组成。     

Progress in Danube Loess and Paleoenvironment Study

Danube loess, located at the westernmost part of the widespread Eurasian loess belt, is one of the most well-preserved aeolian dust deposits in Europe with the basal age dating back over 1 Ma. Owing to its unique location and formation processes, Danube loess plays an important role in understanding the linkage of climate changes in different climate regimes over Eurasian continent and paleoclimatic changes in middle-high northern latitudes. Major research advances of the Danube loess, including compositions, provenance, chronology, stratigraphy and paleoenvironment changes were systematically reviewed and the focuses of future research were suggested. To better understand loess provenance, the compositions of sediments in all the potential source areas should be investigated, and methodological study of provenance indicators and application of multi-proxies approaches need to be carried out. Chronologically and stratigraphically, feldspar luminescence dating and tephrochronology methods should be widely used, and the establishment of a uniform stratigraphic framework and correlation scheme should be constrained by precise chronology. In terms of the paleoenvironment, it is necessary to conduct high-resolution multi-proxies reconstruction of paleoenviroment for the entire loess-paleosol sequence, extending from the last interglacial period (130 ka to present) to interval of last 1 Ma. The future progress in Danube loess is crucial to improving the study of continental paleoclimate comparison and paleoclimate dynamics over the Eurasian loess region.     

毛乌素沙区1961-2016年降水特征

基于毛乌素沙区10个气象站1961-2016年观测资料，应用Mann-Kendall方法和t检验法对各气象站年降水量进行了突变检验，借助小波分析讨论了各气象站年降水量的周期特征，根据降水量等值线划分结果对整个研究区分区分析了年、季、月和日尺度上的降水变化特征，并在两个时段上分析了季节性降水的差异。结果表明：毛乌素沙区年降水量空间特征差异明显，东部亚区呈上升趋势，中西部亚区呈下降趋势，但变化趋势不显著且无突变发生；降水年内分配不均，干湿季分明，降水集中在5-9月，夏秋季降水占全年降水比重大，季、月和日尺度降水量存在梯度递减变化；年降水量的年际变化过程存在多重时间尺度的自相似结构；近26年的冬春季降水增加显著，但降水波动幅度小于前30年。     

Interactive Effects of Ultraviolet Radiation and Dissolved Organic Carbon on Phytoplankton Growth and Photosynthesis in Sanya Bay,Northern South China Sea

Ocean Science Journal - The effects of a simulated climate change scenario, i.e., increased ultraviolet radiation (UVR) and dissolved organic carbon (DOC), on the growth and photosynthesis of...     

塑性极限分析鱼雷锚锚尖贯入阻力

鱼雷锚安装过程中,锚尖形状影响尖部贯入阻力进而影响贯入深度。基于塑性极限分析理论下限法分析不同锚尖长径比x的椭圆形锚尖的贯入阻力和贯入阻力系数,并考虑了贯入深度、锚-土界面摩擦对贯入阻力以及贯入阻力系数的影响。结果表明:(1)锚-土界面光滑时,锚尖贯入阻力系数随着锚尖长径比的增大而减小;锚-土界面粗糙时,锚尖贯入阻力系数随着锚尖长径比的增大而增大。(2)摩擦力对贯入阻力系数的影响随着ξ增大而增大。(3)随着埋置深度增加,贯入阻力系数受x影响最小时所对应的摩擦系数逐渐减小。(4)当锚-土界面摩擦系数ω 0.75时,工程中可选用ξ1的锚尖用以减小端部贯入阻力;当ω0.26时,ξ1的锚尖提供更小的端部贯入阻力。锚尖长径比ξ=0和ξ=1的下限解与前人研究的桩基和圆形结构的理论解较为一致,进一步验证了所提出的椭圆形锚尖下限法模型的可行性。     

海洋资源开发与海洋工程地质——第二届国际海洋工程地质学术研讨会(ISMEG 2019)总结

2019年10月18~20日,第二届国际海洋工程地质学术研讨会(ISMEG 2019)在中国大连成功召开。本次研讨会是在国际工程地质与环境协会(IAEG)架构下由海洋工程地质委员会(C34)主办,海岸与近海工程国家重点实验室(大连理工大学)承办的全球性海洋工程地质学术研讨会。研讨会以"海洋资源开发与海洋工程地质"为主题,针对海洋土工程性质、海洋地质灾害与工程防护、海洋工程地质原位勘测、监测与试验模拟、海洋资源开发水动力环境与作用、海床沉积物和天然气水合物开采、海洋工程结构基础、海流-结构-海床相互作用等7个专题设置了10个特邀报告、21个主题报告及71个学术报告。作为国内外海洋工程地质研究者交流、分享、合作、创新的平台,国际海洋工程地质学术研讨会二度在我国召开,是对我国海洋工程地质学科快速发展的肯定,同时也对我国海洋工程地质研究取得高水平成果和成果转化提出了更高要求。     

东昆仑夏日哈木退变质榴辉岩地球化学、年代学特征及其地质意义

本文对东昆仑夏日哈木退变质榴辉岩开展岩石地球化学和年代学研究，探讨其原岩性质和构造背景。岩石SiO₂含量为46.77%~49.31%，Al₂O₃含量为13.6%~14.6%，TiO₂含量为0.93%~2.29%，全碱（K₂O+Na₂O）含量为1.61%~2.66%，原岩属亚碱性玄武岩系列中的拉斑玄武岩。（La/Yb）_N=0.98~1.63，（La/Sm）_N=0.98~1.41，δEu=1.10~1.28，稀土元素球粒陨石标准化图呈弱Eu正异常的右倾型，岩石相对富集大离子亲石元素Rb、Ba和不相容元素U，相对亏损高场强元素Zr、Hf，Hf/Th=0.59~0.97，Th/Yb=0.13~0.27，显示其原岩具E-MORB特征。退变质榴辉岩的锆石Th/U比值为0.002~0.091，为变质成因锆石，其锆石SIMS U-Pb年龄为414.2 ±7.3 Ma，代表了退变质榴辉岩的峰变质年龄，结合区域地质背景，认为该岩石形成于早泥盆世早期由碰撞作用向碰撞后伸展作用转换的构造环境。